✍️ Arts/Lit A chemist die after exposing in dimethyl mercury

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Jmrie_

in memoriam 1995-2021
Legendary
Dimethylmercury
Dimethylmercury ((You do not have permission to view the full content of this post. Log in or register now.You do not have permission to view the full content of this post. Log in or register now.3)2You do not have permission to view the full content of this post. Log in or register now.) is an You do not have permission to view the full content of this post. Log in or register now.. This colorless liquid is one of the strongest known You do not have permission to view the full content of this post. Log in or register now..You do not have permission to view the full content of this post. Log in or register now. It is described as having a slightly sweet smell, although inhaling enough vapor to detect its odor would be hazardous.You do not have permission to view the full content of this post. Log in or register now.

Dimethylmercury
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150px-Dimethyl-mercury-3D-vdW.webp
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DimethylmercuryYou do not have permission to view the full content of this post. Log in or register now.
Identifiers
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3D model (You do not have permission to view the full content of this post. Log in or register now.)
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3600205
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You do not have permission to view the full content of this post. Log in or register now. 209-805-3
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25889
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  • InChI=1S/2CH3.Hg/h2*1H3; 7px-Yes_check.svg.webp
    Key: ATZBPOVXVPIOMR-UHFFFAOYSA-N 7px-Yes_check.svg.webp
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  • C[Hg]C
Properties
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HgC
2H
6
You do not have permission to view the full content of this post. Log in or register now. 230.66 g mol−1
Appearance Colorless liquid
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You do not have permission to view the full content of this post. Log in or register now. 2.961 g mL−1
You do not have permission to view the full content of this post. Log in or register now. −43 °C (−45 °F; 230 K)
You do not have permission to view the full content of this post. Log in or register now. 93 to 94 °C (199 to 201 °F; 366 to 367 K)
You do not have permission to view the full content of this post. Log in or register now. (nD)
1.543
Thermochemistry
You do not have permission to view the full content of this post. Log in or register now. (ΔfHo298)
57.9–65.7 kJ mol−1
Hazards
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You do not have permission to view the full content of this post. Log in or register now. DANGER
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H300, H310, H330, H373, H410
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P260, P264, P273, P280, P284, P301+310
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80px-NFPA_704.svg.webp
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You do not have permission to view the full content of this post. Log in or register now. 5 °C (41 °F; 278 K)


very toxic


watch her story




short bio

Karen Wetterhahn
Karen Wetterhahn (October 16, 1948 – June 8, 1997) was a professor of You do not have permission to view the full content of this post. Log in or register now. at You do not have permission to view the full content of this post. Log in or register now., New Hampshire, who specialized in toxic metal exposure. She died of You do not have permission to view the full content of this post. Log in or register now. at the age of 48 due to accidental exposure to the organic You do not have permission to view the full content of this post. Log in or register now. compound You do not have permission to view the full content of this post. Log in or register now. (Hg(CH3)2). Protective gloves in use at the time of the incident provided insufficient protection, and exposure to only a few drops of the chemical absorbed through the gloves proved to be fatal after less than a year.
 
Dimethylmercury is extremely toxic and dangerous to handle. Absorption of doses as low as 0.1 You do not have permission to view the full content of this post. Log in or register now. can result in severe mercury poisoning.You do not have permission to view the full content of this post. Log in or register now. The risks are enhanced because of the high You do not have permission to view the full content of this post. Log in or register now. of the liquid.You do not have permission to view the full content of this post. Log in or register now.

Permeation tests showed that several types of disposable latex or polyvinyl chloride gloves (typically, about 0.1 mm thick), commonly used in most You do not have permission to view the full content of this post. Log in or register now.and clinical settings, had high and maximal rates of permeation by dimethylmercury within 15 seconds.You do not have permission to view the full content of this post. Log in or register now. The American You do not have permission to view the full content of this post. Log in or register now. advises handling dimethylmercury with highly resistant laminated gloves with an additional pair of abrasion-resistant gloves worn over the laminate pair, and also recommends using a face shield and working in a fume hood.You do not have permission to view the full content of this post. Log in or register now.You do not have permission to view the full content of this post. Log in or register now.

Dimethylmercury is metabolized after several days to methylmercury You do not have permission to view the full content of this post. Log in or register now.. Methylmercury crosses the You do not have permission to view the full content of this post. Log in or register now. easily probably owing to formation of a You do not have permission to view the full content of this post. Log in or register now. with You do not have permission to view the full content of this post. Log in or register now..You do not have permission to view the full content of this post. Log in or register now. It is eliminated from the organism slowly, and therefore has a tendency to You do not have permission to view the full content of this post. Log in or register now.. The symptoms of You do not have permission to view the full content of this post. Log in or register now. may be delayed by months, resulting in cases in which a diagnosis is ultimately discovered, but only at the point in which it is too late for an effective treatment regimen to be successful.You do not have permission to view the full content of this post. Log in or register now.

The toxicity of dimethylmercury was highlighted with the death of You do not have permission to view the full content of this post. Log in or register now. a professor of chemistry at You do not have permission to view the full content of this post. Log in or register now. in 1997. Professor Wetterhahn specialized in heavy metal poisoning. After spilling a few drops of this compound on her You do not have permission to view the full content of this post. Log in or register now., the barrier was compromised and within minutes it was absorbed into her skin. It circulated through her body and accumulated in her brain resulting in her death ten months later.You do not have permission to view the full content of this post. Log in or register now. This accident is a common toxicology case-study and directly resulted in improved safety procedures for chemical-protection clothing and fume use which are now used when any exposure to such severely toxic and/or highly penetrative substances is possible (e.g., in chemical munitions stockpiles and decontamination facilities).[
 
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